I would uninstall lightroom on the old computer before you install it on the new. In photoshop you can deactivate, but in LR I don't see that option. You could always click on help, registration, and change your registration to trial? that might help in releasing the serial number. In the end if it doesn't work correctly the worst case scenario is that you'll spend some time on adobe's automated phone system to get the serial number to register again correctly.
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